論文雑誌「Chemistry – An Asian Journal」のカバーピクチャーを制作しました［株式会社ブリヂストン］
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Wiley社が発行する学術雑誌 Chemistry – An Asian Journal
2022年12月号 Front Coverに選ばれました。
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先端材料部門 革新材料技術戦略・研究部 革新ゴム材料研究課
福島里佳様
先端材料部門 革新材料技術戦略・研究部 革新ゴム材料研究課
福島里佳様
Journal
Chemistry – An Asian Journal
December 1, 2022, Volume 17, Issue 23 Link
December 1, 2022, Volume 17, Issue 23 Link
Non-π-Allyl Mechanism for the 1,4-cis-Butadiene Polymerization: Theoretical Study of Polymerization via Insertion of Butadiene into Al−C Bond with Cationic Gadolinium Metallocene. (Chem. Asian J. 23/2022)
Rika Fukushima, Dr. Olivier Tardif, Dr. Shojiro Kaita, Dr. Yasuo Wakatsuki, Yukihiro Kojima, Prof. Nobuaki Koga
A novel mechanism for the polymerization of butadiene by cationic gadolinium metallocene in the presence of excess Al(iBu)3 is presented. The absence of an initial Gd-alkyl bond in this reaction system precludes the conventional mechanism by coordinative chain transfer polymerization (CCTP). Density functional theory (DFT) analysis indicates a mechanism in which cationic Gd assists butadiene insertion into one of the Al–C bonds of Al(iBu)3, explaining the 1,4-cis selectivity unique to this catalytic system. More information can be found in the Research Article by Rika Fukushima et al.
Rika Fukushima, Dr. Olivier Tardif, Dr. Shojiro Kaita, Dr. Yasuo Wakatsuki, Yukihiro Kojima, Prof. Nobuaki Koga
A novel mechanism for the polymerization of butadiene by cationic gadolinium metallocene in the presence of excess Al(iBu)3 is presented. The absence of an initial Gd-alkyl bond in this reaction system precludes the conventional mechanism by coordinative chain transfer polymerization (CCTP). Density functional theory (DFT) analysis indicates a mechanism in which cationic Gd assists butadiene insertion into one of the Al–C bonds of Al(iBu)3, explaining the 1,4-cis selectivity unique to this catalytic system. More information can be found in the Research Article by Rika Fukushima et al.
