論文雑誌「Chemical Science」のカバーピクチャーを制作しました[名古屋大学]

弊社で制作しました名古屋大学 南保正和先生のカバーアートが
イギリスの王立化学会発行の学術雑誌 Chemical Science
2021年8月号に選ばれました。

Chemical Science カバーピクチャー 科学イラスト 論文表紙絵 アートアクション 名古屋大学
Client
名古屋大学
トランスフォーマティブ生命分子研究所 
南保正和先生
Journal
Chemical Science
21 August 2021, Issue 31,  Page 10399 to 10674 Link
Synthesis and enantioseparation of chiral Au13 nanoclusters protected by bis-N-heterocyclic carbene ligands
Hong Yi, Kimberly M. Osten, Tetyana I. Levchenko, Alex J. Veinot, Yoshitaka Aramaki, Takashi Ooi, Masakazu Nambo and Cathleen M. Crudden

A series of chiral Au13 nanoclusters were synthesized via the direct reduction of achiral dinuclear Au(I) halide complexes ligated by ortho-xylyl-linked bis-N-heterocyclic carbene (NHC) ligands. A broad range of functional groups are tolerated as wingtip substituents, allowing for the synthesis of a variety of functionalized chiral Au13 nanoclusters. Single crystal X-ray crystallography confirmed the molecular formula to be [Au13(bisNHC)5Cl2]Cl3, with a chiral helical arrangement of the five bidentate NHC ligands around the icosahedral Au13 core. This Au13 nanocluster is highly luminescent, with a quantum yield of 23%. The two enantiomers of the Au13 clusters can be separated by chiral HPLC, and the isolated enantiomers were characterized by circular dichroism spectroscopy. The clusters show remarkable stability, including configurational stability, opening the door to further investigation of the effect of chirality on these clusters.

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  • Chemical Science
  • 名古屋大学
  • RSC
  • Cover Art
  • カバーピクチャー
  • 学術雑誌・ジャーナル
  • イラスト
  • 論文
  • 表紙絵
  • 制作実績